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Dielectric Constant of Commonly Used Polymer Plastics

June 26, 2024

The transmission speed of the signal in the 5G era will also be much faster than that of the 4G signal, which requires the material to have a small interference with the signal and a small dielectric constant to ensure that the transmission of big data is not interfered with. So what is the dielectric constant, the dielectric constant of various materials and how much? Medium in the applied electric field will produce induced charge and weaken the electric field, the medium of the electric field reduction and the original applied electric field (in a vacuum) of the ratio of the relative permittivity (relative permittivity or dielectric constant), also known as the induced electric rate, and frequency-related. The dielectric constant is the product of the relative permittivity and the absolute permittivity in vacuum. If a material with a high dielectric constant is placed in an electric field, the strength of the field decreases appreciably within the dielectric. The relative permittivity of an ideal conductor (metal) is infinity.


According to the dielectric constant of the substance can be judged by the polarity of the polymer material. Usually, the relative permittivity greater than 3.6 of the material for polar substances; relative permittivity in the range of 2.8 ~ 3.6 of the material for weakly polar substances; relative permittivity less than 2.8 for non-polar substances.


Similarly, we based on the polarity of polymer materials can also be roughly inferred material dielectric constant size, more polar groups, high dielectric constant, less polar groups dielectric constant is small.


The following is the size of the dielectric constant of common materials:

Polymers Minimum value Maximum value
HIPS Flame Retardant V0 2 3
PCTFE - Polymonochlorotrifluoroethylene 2 3
PMMA - Polymethylmethacrylate/ acrylic 2 5
FEP - Fluorinated Ethylene Propylene 2.1 2.1
PFA - Perfluoroalkoxy 2.1 2.1
PTFE - Polytetrafluoroethylene 2.1 2.1
PMP - Polymethylpentene 2.1 3.6
hdpe - High Density Polyethylene 2.3 2.3
LDPE - Low Density Polyethylene 2.3 2.3
LLDPE - Linear Low Density Polyethylene 2.3 2.3
PMP Mineral Filled 2.3 2.3
PP , 10-40% Mineral Filled 2.3 2.3
PP, 10-40% Talc Filled 2.3 2.3
PP (Polypropylene) Copolymer 2.3 2.3
PP (Polypropylene) Homopolymer 2.3 2.3
PP, Impact Modified 2.3 2.3
UHMWPE - Ultra high molecular weight polyethylene 2.3 2.3
PMP 30% Glass Fiber-reinforced 2.4 2.4
PS ( Polystyrene ) Crystal 2.4 2.7
PS, High Heat 2.4 2.7
HIPS - High Impact Polystyrene 2.4 4.8
ABS High Heat 2.4 5
ABS High Impact 2.4 5
PS (Polystyrene) 30% glass fiber 2.5 2.5
EVA - Ethylene Vinyl Acetate 2.5 3
SAN - Styrene Acrylonitrile 2.5 3.4
ECTFE 2.57 2.59
ETFE - Ethylene Tetrafluoroethylene 2.6 2.6
PP - Polypropylene 10-20% Glass Fiber 2.6 2.6
PP, 30-40% Glass Fiber-reinforced 2.6 2.6
PPE - Polyphenylene Ether 2.7 2.7
PPE, Flame Retardant 2.7 2.7
PE - Polyethylene 30% Glass Fiber 2.7 2.8
ABS - Acrylonitrile Butadiene Styrene 2.7 3.2
SMA - Styrene Maleic Anhydride 2.8 2.8
ABS Flame Retardant 2.8 3
MABS - Transparent Acrylonitrile Butadiene Styrene 2.8 3
PC - polycarbonate, high heat 2.8 3.8
PPE, 30% Glass Fiber-reinforced 2.9 2.9
ABS/PC Blend - Acrylonitrile Butadiene Styrene/Polycarbonate Blend 2.9 3.2
PMMA (Acrylic) Impact Modified 2.9 3.7
PBT - Polybutylene Terephthalate 2.9 4
PA 66, Impact Modified 2.9 5
PC/PBT Blend - Polycarbonate/Polybutylene Terephthalate Blend 2.95 3.14
PTFE, 25% Glass Fiber-reinforced 3 3
PSU - Polysulfone 3 3.2
PPS - Polyphenylene Sulfide 3 3.3
ASA/PC Blend - Acrylonitrile Styrene Acrylate/Polycarbonate Blend 3 3.4
PC (Polycarbonate) 20-40% Glass Fiber 3 3.5
PC (Polycarbonate) 20-40% Glass Fiber Flame Retardant 3 3.8
CP - Cellulose Proprionate 3 4
LCP Glass Fiber-reinforced 3 4
PA 6-10 - Polyamide 6-10 3 4
PBT, 30% Glass Fiber 3 4
PEI , 30% Glass Fiber-reinforced 3 4
PEI, Mineral Filled 3 4
PET - Polyethylene Terephtalate 3 4
PET, 30% Glass Fiber-reinforced 3 4
PETG - Polyethylene Terephtalate Glycol 3 4
POM ( Acetal ) Low Friction 3 4
PVC Rigid 3 4
PVC, Plasticized 3 5
PVC, Plasticized Filled 3 5
LCP Mineral-filled 3 5.9
CPVC - Chlorinated Polyvinyl Chloride 3 6
PVDC - Polyvinylidene Chloride 3 6
CAB - Cellulose Acetate Butyrate 3 7
CA - Cellulose Acetate 3 8
PA 11, Conductive 3 9
PA 11, Flexible 3 9
PA 11, Rigid 3 9
PA 12 (Polyamide 12), Conductive 3 9
PA 12, Fiber-reinforced 3 9
PA 12, Flexible 3 9
PA 12, Glass Filled 3 9
PA 12, Rigid 3 9
SRP - Self-reinforced Polyphenylene 3.1 3.1
ABS/PC Blend 20% Glass Fiber 3.1 3.2
PEI - Polyetherimide 3.1 3.2
PI - Polyimide 3.1 3.55
ASA/PC Flame Retardant 3.2 3.2
PEEK - Polyetheretherketone 3.2 3.2
SMMA - Styrene Methyl Methacrylate 3.2 3.2
PEEK 30% Carbon Fiber-reinforced 3.2 3.4
SAN, 20% Glass Fiber-reinforced 3.2 3.8
PMMA (Acrylic) High Heat 3.2 4
LCP - Liquid Crystal Polymer 3.3 3.3
PAR - Polyarylate 3.3 3.3
PEKK (Polyetherketoneketone), Low Cristallinity Grade 3.3 3.3
SMA, 20% Glass Fiber-reinforced 3.3 3.3
ASA - Acrylonitrile Styrene Acrylate 3.3 3.8
PPS, 20-30% Glass Fiber-reinforced 3.3 3.8
PC/PBT blend, Glass Filled 3.3 3.9
PEEK 30% Glass Fiber-reinforced 3.3 4.2
POM - Polyoxymethylene (Acetal) 3.3 4.7
PPSU - Polyphenylene Sulfone 3.4 3.5
PA 46 - Polyamide 46 3.4 3.8
PA 66, Impact Modified, 15-30% Glass Fiber 3.4 4.2
Amorphous TPI Blend, Ultra-high heat, Chemical Resistant (Standard Flow) 3.5 3.5
PESU - Polyethersulfone 3.5 4.1
PA 66, 30% Glass Fiber 3.5 5.6
PSU, 30% Glass finer-reinforced 3.6 3.7
PPA, 33% Glass Fiber-reinforced – High Flow 3.7 3.9
PARA (Polyarylamide), 30-60% glass fiber 3.9 4.5
PAI - Polyamide-Imide 3.9 7.3
PPS, 40% Glass Fiber-reinforced 4 4
PPA, 30% Mineral-filled 4 4.2
POM (Acetal) Impact Modified 4 4.3
PA 46, 30% Glass Fiber 4 4.6
PA 6 - Polyamide 6 4 5
PA 66 - Polyamide 6-6 4 5
PA 66, 30% Mineral filled 4 5
PESU 10-30% glass fiber 4.2 4.3
PAI, 30% Glass Fiber 4.2 6.5
PPA - Polyphthalamide 4.3 4.3
PPA, 33% Glass Fiber-reinforced 4.4 4.6
PPA, 45% Glass Fiber-reinforced 4.4 4.6
PA 11 - (Polyamide 11) 30% Glass fiber reinforced 4.8 4.8
EVOH - Ethylene Vinyl Alcohol 4.8 5.6
PPS, Glass fiber & Mineral-filled 5 5
PVDF - Polyvinylidene fluoride 6 9


At present, we are discussing more 5G engineering plastics, mainly divided into thin film products (LCP, PI, etc. used in circuit boards, antennas), and structural parts (injection molding), such as low dielectric LCP, PBT, PPO, PPS and so on. Selection of materials to meet both low dielectric constant and mechanical properties, chemical properties, electrical properties and other factors. The dielectric constant of modified plastics is related to the molecular structure of the base material, as well as the dielectric constant of the reinforcement/filler material.



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